ARTICLE
High-performance concrete (HPC) intended for severe environments requires exceptional strength and durability. This study investigates the synergistic potential of silica fume (SF) and nano-silica (NS) in a ternary cementitious system (cement-SF-NS) to overcome the limitations of using single supplementary cementitious materials. The objectives were to determine the optimal SF/NS combination and to elucidate their synergistic effects on the performance and microstructure. An experimental matrix was designed, incorporating SF (0–20%) and NS (0–2%). The methods comprised evaluating workability, mechanical strength (from 3 to 91 days), chloride penetration resistance (via the RCM test), and microstructural evolution (assessed using isothermal calorimetry, XRD, SEM, and MIP). The results revealed that the ternary system containing 15% SF and 1.5% NS yielded optimal performance. This mix achieved 28-day compressive and flexural strengths of 85.6 MPa and 9.5 MPa, representing improvements of 88.2% and 76.5%, respectively, over the plain cement control. Furthermore, this combination reduced the chloride migration coefficient by 59.1%. Microstructural analyses confirmed a synergistic mechanism whereby NS acted as a potent nucleation catalyst, accelerating early-age hydration, while SF provided sustained pozzolanic reactivity. Together, they promoted the formation of denser C–S–H gel and refined the pore structure across both micro- and nano-scales. This work provides a scientifically grounded, optimal ternary design that simultaneously enhances workability, strength, and durability. It thus offers a robust solution for advanced concrete in aggressive service environments.
REFERENCES
[1] Liu G, Shan C, Hu S, Sun P, Wang X, Zhao L, et al. Experimental study on the mechanical properties and durability of high-performance concrete for jacking prestressed concrete cylinder pipe. Constr Build Mater. 2025;500:144163. doi:10.1016/j.conbuildmat.2025.144163.
[2] Inayathulla M, Ahmad S, Iqbal T, Al-Osta MA, Najamuddin SK, Hanif A. High-strength self-compacting concrete incorporating red mud: development and comprehensive performance evaluation. Case Stud Constr Mater. 2026;24:e05714. doi:10.1016/j.cscm.2025.e05714.
[3] Kalyana Chakravarthy PR, Namratha K. Strength and durability properties of high strength self compacting concrete. Mater Today Proc. 2022;69:896–900. doi:10.1016/j.matpr.2022.07.365.
[4] Hosseini Mehrab A, Yaqubi E, Amirfakhrian S, Ghalehnovi M. Multidimensional fracture assessment of SCM-modified high-performance hybrid fiber-reinforced concrete: comparative insights from WFM, SEM, and BEM approaches. Results Eng. 2025;28:107800. doi:10.1016/j.rineng.2025.107800.
[5] Karaaslan C. Unary, binary and ternary use of slag, nano-CaCO3, and cement to enhance freeze-thaw durability in fly ash-based geopolymer concretes. J Build Eng. 2025;99:111631. doi:10.1016/j.jobe.2024.111631.
[6] Tran HB, Phan VT. Potential usage of fly ash and nano silica in high-strength concrete: laboratory experiment and application in rigid pavement. Case Stud Constr Mater. 2024;20:e02856. doi:10.1016/j.cscm.2024.e02856.
[7] Lekhya A, Kumar NS. A study on the effective utilization of ultrafine fly ash and silica fume content in high-performance concrete through an experimental approach. Heliyon. 2024;10(22):e39678. doi:10.1016/j.heliyon.2024.e39678; 39624283
[8] Smarzewski P. Influence of silica fume on mechanical and fracture properties of high performance concrete. Procedia Struct Integr. 2019;17:5–12. doi:10.1016/j.prostr.2019.08.002.
[9] Adebanjo AU, Abbas YM, Shafiq N, Khan MI, Ahmad Farhan S, Masmoudi R. Optimizing nano-TiO2 and ZnO integration in silica-based high-performance concrete: mechanical, durability, and photocatalysis insights for sustainable self-cleaning systems. Constr Build Mater. 2024;446:138038. doi:10.1016/j.conbuildmat.2024.138038.
[10] Sun H, Luo L, Li X, Yuan H. The treated recycled aggregates effects on workability, mechanical properties and microstructure of ultra-high performance concrete co-reinforced with nano-silica and steel fibers. J Build Eng. 2024;86:108804. doi:10.1016/j.jobe.2024.108804.
[11] Wu Z, Khayat KH, Shi C. Effect of nano-SiO2 particles and curing time on development of fiber-matrix bond properties and microstructure of ultra-high strength concrete. Cem Concr Res. 2017;95:247–56. doi:10.1016/j.cemconres.2017.02.031.
[12] Zhang MH, Islam J. Use of nano-silica to reduce setting time and increase early strength of concretes with high volumes of fly ash or slag. Constr Build Mater. 2012;29:573–80. doi:10.1016/j.conbuildmat.2011.11.013.
[13] Kaur H, Kulthaweepisit N, Tran TNH, Jaturapitakkul C, Tangchirapat W. Investigation of strength and water permeability of sustainable high-performance concrete containing high-volume ground bottom ash blended with fly ash and nano-silica. J Build Eng. 2024;90:109428. doi:10.1016/j.jobe.2024.109428.
[14] Khan MH, Zhao Q, Ali Sikandar M, Khan B, Han Z, Khan MS. Evaluation of mechanical strength, gamma-ray shielding characteristics, and ITZ microstructural properties of heavyweight concrete using nano-silica (SiO2) and barite aggregates. Constr Build Mater. 2024;419:135483. doi:10.1016/j.conbuildmat.2024.135483.
[15] Fallah-Valukolaee S, Mousavi R, Arjomandi A, Nematzadeh M, Kazemi M. A comparative study of mechanical properties and life cycle assessment of high-strength concrete containing silica fume and nanosilica as a partial cement replacement. Structures. 2022;46:838–51. doi:10.1016/j.istruc.2022.10.024.
[16] Abna A, Mazloom M. Flexural properties of fiber reinforced concrete containing silica fume and nano-silica. Mater Lett. 2022;316:132003. doi:10.1016/j.matlet.2022.132003.
[17] Golewski GL. Investigating the effect of using three pozzolans (including the nanoadditive) in combination on the formation and development of cracks in concretes using non-contact measurement method. Adv Nano Res. 2024;16:217–29. doi:10.12989/anr.2024.16.3.217.
[18] Golewski GL. Using digital image correlation to evaluate fracture toughness and crack propagation in the mode I testing of concretes involving fly ash and synthetic nano-SiO2. Mater Res Express. 2024;11(9):095504. doi:10.1088/2053-1591/ad755e.
[19] Wang Y, Fan X, Wu R, Lin H, Feng W. Experimental study on long-term impermeability of recycled aggregate concrete mixed with crystalline admixture and waste glass powder. J Clean Prod. 2024;458:142551. doi:10.1016/j.jclepro.2024.142551.
[20] Das SK, Mustakim SM, Adesina A, Mishra J, Alomayri TS, Assaedi HS, et al. Fresh, strength and microstructure properties of geopolymer concrete incorporating lime and silica fume as replacement of fly ash. J Build Eng. 2020;32:101780. doi:10.1016/j.jobe.2020.101780.
[21] Memon FA, Nuruddin MF, Shafiq N. Effect of silica fume on the fresh and hardened properties of fly ash-based self-compacting geopolymer concrete. Int J Miner Metall Mater. 2013;20(2):205–13. doi:10.1007/s12613-013-0714-7.
[22] Wu Z, Shi C, Khayat KH, Wan S. Effects of different nanomaterials on hardening and performance of ultra-high strength concrete (UHSC). Cem Concr Compos. 2016;70:24–34. doi:10.1016/j.cemconcomp.2016.03.003.
[23] Luo Z, Zhi T, Liu X, Yin K, Pan H, Feng H, et al. Effects of different nanomaterials on the early performance of ultra-high performance concrete (UHPC): C-S–H seeds and nano-silica. Cem Concr Compos. 2023;142:105211. doi:10.1016/j.cemconcomp.2023.105211.
[24] Lai G, Sun Z, Zhang S, Liao F, Li S, Qian J, et al. Nano-C-S-H seeds reinforced UHPC containing silica fume and metakaolin: mechanism analysis and carbon footprint assessment. Case Stud Constr Mater. 2026;24:e05698. doi:10.1016/j.cscm.2025.e05698.
[25] Juenger MCG, Siddique R. Recent advances in understanding the role of supplementary cementitious materials in concrete. Cem Concr Res. 2015;78:71–80. doi:10.1016/j.cemconres.2015.03.018.
[26] Sanchez F, Sobolev K. Nanotechnology in concrete—A review. Constr Build Mater. 2010;24(11):2060–71. doi:10.1016/j.conbuildmat.2010.03.014.
[27] Rong Z, Sun W, Xiao H, Jiang G. Effects of nano-SiO2 particles on the mechanical and microstructural properties of ultra-high performance cementitious composites. Cem Concr Compos. 2015;56:25–31. doi:10.1016/j.cemconcomp.2014.11.001.
[28] Hartono J Purwanto, Ekaputri JJ. Effects of HVFA with the addition of bottom ash, NaOH, and CaCO3 on self-compacting concrete (SCC) in tidal environments. Case Stud Constr Mater. 2025;22(6):e04593. doi:10.1016/j.cscm.2025.e04593.
[29] Péra J, Husson S, Guilhot B. Influence of finely ground limestone on cement hydration. Cem Concr Compos. 1999;21(2):99–105. doi:10.1016/S0958-9465(98)00020-1’s.
[30] Tong LY, Cai Y, Liu QF. Carbonation modelling of hardened cementitious materials considering pore structure characteristics: a review. J Build Eng. 2024;96:110547. doi:10.1016/j.jobe.2024.110547.
[31] Zhang X, Li M, Wang C, Li Y, Fan Y, Liu X, et al. Multi-parameter analysis of nano-SiO2 modified recycled aggregate concrete: fatigue damage and microscopic mechanisms. Structures. 2025;79:109414. doi:10.1016/j.istruc.2025.109414.
[32] Zhang S, Lu X, Wang J, Deng X, Tan H. Improving the properties of phosphogypsum-based clinker-free cement system by in-situ precipitation of ettringite seeds: strength, hydration, microstructure and sustainability. Mater Today Commun. 2025;44(1):111982. doi:10.1016/j.mtcomm.2025.111982.
[33] Hu Z, Yang Y, Zhang H. Durability and damage evolution of steel fiber and Nano-SiO2 reinforced concrete under freeze-thaw and salt erosion environments based on acoustic emission and Computed Tomography analysis. J Build Eng. 2025;115:114595. doi:10.1016/j.jobe.2025.114595.
[34] Karimipour A, Ghalehnovi M, Edalati M, de Brito J. Properties of fibre-reinforced high-strength concrete with nano-silica and silica fume. Appl Sci. 2021;11(20):9696. doi:10.3390/app11209696.
[35] Olivier G, Combrinck R, Kayondo M, Boshoff WP. Combined effect of nano-silica, super absorbent polymers, and synthetic fibres on plastic shrinkage cracking in concrete. Constr Build Mater. 2018;192(1):85–98. doi:10.1016/j.conbuildmat.2018.10.102.
APA Style
Du, M., Li, Y., Deng, Y. (2026). Combined effect of silica fume and nano-silica in ternary cementitious systems for enhanced high-strength concrete performance. ZKG International, 105–117. https://doi.org/10.32604/zkg.2026.078318
Vancouver Style
Du M, Li Y, Deng Y. Combined effect of silica fume and nano-silica in ternary cementitious systems for enhanced high-strength concrete performance. ZKG Int.. 2026;:105–117. https://doi.org/10.32604/zkg.2026.078318
IEEE Style
M. Du, Y. Li, and Y. Deng, “Combined effect of silica fume and nano-silica in ternary cementitious systems for enhanced high-strength concrete performance,” ZKG Int., pp. 105–117, 2026. https://doi.org/10.32604/zkg.2026.078318